Section 1. Chemical product and company identification
Product Name : Ethanol
Synonym :
Ethyl alcohol; Alcohol; Alcohol anhydrous; Algrain; Anhydrol; Denatured ethanol; Ethyl hydrate; Ethyl hydroxide; Jaysol; Jaysol S; Methylcarbinol; SD Alchol 23-hydrogen; Tecsol; C2H5OH; Absolute ethanol; Cologne spirit; Fermentation alcohol; Grain alcohol; Molasses alcohol; Potato alcohol; Aethanol; Aethylalkohol; Alcohol, dehydrated; Alcohol, diluted; Alcool ethylique; Alcool etilico; Alkohol; Cologne spirits; Denatured alcohol CD-10; Denatured alcohol CD-5; Denatured alcohol CD-5a; Denatured alcohol SD-1; Denatured alcohol SD-13a; Denatured alcohol SD-17; Denatured alcohol SD-23a; Denatured alcohol SD-28; Denatured alcohol SD-3a; Denatured alcohol SD-30; Denatured alcohol SD-39b; Denatured alcohol SD-39c; Denatured alcohol SD-40m; Etanolo; Ethanol 200 proof; Ethyl alc; Etylowy alkohol; EtOH; NCI-C03134; Spirits of wine; Spirt; Thanol; Alkoholu etylowego; Ethanol, solution; Ethyl alcohol anhydrous; SD alcohol 23-hydrogen; UN 1170; Tecsol C; Alcare Hand Degermer; Absolute alcohol; Cologne spirits (alcohol); Denatured alcohol; Ethanol, silent spirit; Ethylol; Punctilious ethyl alcohol; Pyro; Spirit; Synasol; USI in oval; Ethanol standard
Material uses : Other non-specified industry: MANUFACTURE OF ACETALDEHYDE AND OTHER CHEMICALS; SOLVENTS; ANTIFREEZE AND BRAKE FLUIDS; FUEL
CAS -NUMBER : #64-17-5
Section 2. Hazards identification
Physical State : Liquid. [CLEAR, COLORLESS LIQUID WITH A WEAK, ETHEREAL, VINOUS ODOR]
Emergency Overview : WARNING! FLAMMABLE LIQUID AND VAPOR. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CAN CAUSE CANCER.
Flammable liquid. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Avoid contact with skin and clothing. May cause target organ damage, based on animal data. Can ause cancer. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.
Potential acute health effects:
Eyes : Iritating to eyes
Skin : Iritating to skin
Inhalation : Iritating to respetory system
Ingestion : No known significant efects or critical Hazard
Potential chronic health :
CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC. efect Classified A3 (Proven for animals.) by ACGIH.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Medical conditions aggravated by overexposure : Pre-existing disorders involving any target organs mentioned in this MSDSas being at risk may be aggravated by over-exposure to this product.
Section 3. Composition, Information on Ingredients
Ethanol
64-17-5 100
ACGIH TLV (United States, 1/2009).
STEL: 1000 ppm 15 minute(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hour(s).
TWA: 1900 mg/m³ 8 hour(s).
NIOSH REL (United States, 6/2009).
TWA: 1000 ppm 10 hour(s).
TWA: 1900 mg/m³ 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 1000 ppm 8 hour(s).
TWA: 1900 mg/m³ 8 hour(s).
Section 4. First aid measures
Eyes contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Section 5. Fire-fighting measures
Flammability of the product : Flammable.
Auto-ignition temperature : 398.85°C (749.9°F)
Flash point : Close cup : 12.85°C (55.1°F).
Flammable limits : Lower: 3.3% Upper: 19%
Products of combustion : Decomposition products may include the following materials: carbon dioxide, Carbon monoxide
Extinguishing media
Suitable : Use dry chemical, CO2, water spray (fog) or foam.
No suitable : Do not use water jet.
Specials exposure hazard : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal and precaution : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8).
Environmental precaution : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled roduct. Note: see section 1 for emergency contact information and section 13 for waste disposal.
Section 7. Handling and storage
Handling:
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
Storage:
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
Other information:
Label requirement : FLAMMABLE LIQUID AND VAPOR. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CAN CAUSE CANCER.
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